Bismuth trifluoride - Alchetron, The Free Social Encyclopedia
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The first structural proof of bismuth acting as a halogen bond acceptor has been reported in JACS (🔎https://ccdc-info.com/4ht3O93). The unstable adduct CSD entry XUCFAG, which can be regarded as an intermediate in an overall Bi(i) to Bi(iii) oxidation process, displays Bi…I contacts below the sum of the van der Waals radii and elongated C-I bonds. 🔗 https://ccdc-info.com/3YPXbGt #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC)
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